Variation in noble gas isotopic composition of gas samples from the Aegean arc, Greece     

Aya Shimizu  Hirochika Sumino  Keisuke Nagao  Kenji Notsu  Panagiotis Mitropoulos 《Journal of Volcanology and Geothermal Research》2005,140(4):118-339

In contrast to most other arcs with oceanic plate subduction, the Aegean arc is characterized by continent–continent subduction. Noble gas abundances and isotopic compositions of 45 gas samples have been determined from 6 volcanoes along the arc, 2 islands in the back-arc region and 7 sites in the surrounding areas. The ³He/⁴He ratios of the samples ranged from 0.027R_A to 6.2R_A (R_A denotes the atmospheric ³He/⁴He ratio of 1.4×10⁻⁶), demonstrating that even the maximum ³He/⁴He ratio in the region is significantly lower than the maximum ratios of most oceanic subduction systems, which are equal to the MORB value of 8±1 R_A. Regional variations in the ³He/⁴He ratio were observed both along and across the arc. The maximum ³He/⁴He ratio was obtained from Nisyros volcano located in the eastern end of the arc, and the ratio decreased westward possibly reflecting the difference in potential degree of crustal assimilation or the present magmatic activity in each volcano. Across the volcanic arc, the ³He/⁴He ratio decreased with an increasing distance from the arc front, reaching a low ratio of 0.063R_A in Macedonia, which suggested a major contribution of radiogenic helium derived from the continental crust. At Nisyros, a temporal increase in ³He/⁴He ratio due to ascending subsurface magma was observed after the seismic crisis of 1995–1998 and mantle neon was possibly detected. The maximum ³He/⁴He ratio (6.2R_A) in the Aegean region, which is significantly lower than the MORB value, is not probably due to crustal assimilation at shallow depth or addition of slab-derived helium to MORB-like mantle wedge, but inherent characteristics of the subcontinental lithospheric mantle (SCLM) beneath the Aegean arc.  相似文献   

Ore-forming mechanism for the Xiaoxinancha Au-rich Cu deposit in Yanbian,Jilin Province,China: Evidence from noble gas isotope geochemistry of fluid inclusions in minerals   总被引：2，自引：0，他引：2  

KEISUKE Nagao  HIROCHIKA Sumino 《中国科学D辑(英文版)》2008,51(2):216-228

The Xiaoxinancha Au-rich copper deposit is one of important Au-Cu deposits along the continental margin in Eastern China. The deposit consists of two sections: the Beishan mine (North), composed of altered rocks with veinlet-dissemination sulfides and melnicovite-dominated sulfide-quartz veins, and the Nanshan mine (South), composed of pyrrhotite-dominated sulfide-quartz veins and pure sulfide veins. The isotope compositions of noble gases extracted from fluid inclusions in ore minerals, i.e. ratios of 3He/4He, 20Ne/22Ne and40Ar/36Ar are in the ranges of 4.45―0.08 Ra, 10.2―8.8 and 306―430, respectively. Fluid inclusions in minerals from the Nanshan mine have higher 3He/4He and 20Ne/22Ne ratios whereas those from the Beishan mine have lower 3He/4He ratios. The analysis of origin, and evolution of the ore fluids and its relations with the ore-forming stages and the ages of mineralization suggests that the initial hydrothermal fluids probably come from the melts generated by partial melting of oceanic crust with the participation of fluids from the mantle (mantle-plume type)/aesthenosphere. This also corresponds to the continental margin settings during the subduction of Izanagi ocaneic plate towards the palaeo-Asian continent (123―102 Ma). The veinlet-dissemination ore bodies of the Beishan mine were formed through replacement and crystallization of the mixed fluids generated by mixing of the ascending high-temperature boiling fluid with young crustal fluid whereas the melnicovite-dominated sulfide-quartz veins were formed subsequently by filling of the high-temperature ore fluid in fissures. Pyrrhotite-dominated sulfide-quartz veins in the Nanshan mine were formed by filling-deposition-crystallization of the moderate-temperature ore fluids and the pure sulfide veins were formed later by filling-deposition-crystallization of ore substance-rich fluids after boiling of the moderate-temperature ore fluids. The metallogenic dynamic processes can be summarized as: (1) formation of fluidand ore substance-bearing Adakitic magma by degassing, dewatering and partial melting during subduction of the Izanagi plate; (2) separation and formation of ore fluids from the Adakitic magma; and (3) success-sive ascending of the ore fluids and final formation of the Au-rich Cu deposit of veinlet-dissemination and vein types by secondary boiling.  相似文献   

Oxygen isotope signatures in bulk chondrules: Implications for the aqueous alteration and thermal metamorphism on the Allende CV3 parent body     

Iffat Jabeen  Minoru Kusakabe  Keisuke Nagao  Arshad Ali 《Meteoritics & planetary science》2019,54(2):431-451

Precise triple oxygen isotope compositions of 32 Allende bulk chondrules (ABCs) are determined using laser‐assisted fluorination mass spectrometry. Various chemically characterized chondrule types show ranges in δ¹⁸O that vary from ?4.80‰ to +1.10‰ (porphyritic olivine; PO, N = 15), ?3.10‰ to +1.50‰ (porphyritic olivine pyroxene; POP, N = 9), ?3.40‰ to +2.60‰ (barred olivine; BO, N = 4), and ?3.60‰ to +1.30‰ (porphyritic pyroxene; PP, N = 3). Oxygen isotope data of these chondrules yield a regression line referred to as the Allende bulk chondrule line (ABC line, slope = 0.86 ± 0.02). Most of our data fall closer to the primitive chondrule minerals line (PCM line, slope = 0.987 ± 0.013) and the carbonaceous chondrite anhydrous mineral line (CCAM line, slope = 0.94 ± 0.02) than the Allende anhydrous mineral line (AAML, slope = 1.00 ± 0.01) with a maximum δ¹⁸O value (+2.60‰) observed in a BO chondrule and a minimum δ¹⁸O value (?4.80‰) shown by a PO chondrule. Similarly, these chondrules depict variable ?¹⁷O values that range from ?5.65‰ to ?3.25‰ (PO), ?4.60‰ to ?2.80‰ (POP), ?4.95‰ to ?3.00‰ (BO), ?5.30‰ to ?3.20‰ (PP), and ?4.90‰ (CC). A simple model is proposed for the Allende CV3 chondrite with reference to the AAML and PCM line to illustrate the isotopic variations occurred due to the aqueous alteration processes. The estimated temperature ranging from 10 to 130 °C (mean ~60 °C) implies that the secondary mineralization in Allende happened in a warmer and relatively dry environment compared to Murchison. We further propose that thermal metamorphism could have dehydrated the Allende matrix at temperatures between >150 °C and <600 °C.  相似文献   

Primordial and cosmogenic noble gases in the Sutter's Mill CM chondrite          下载免费PDF全文

Ryuji Okazaki  Keisuke Nagao 《Meteoritics & planetary science》2017,52(4):669-689

The Sutter's Mill (SM) CM chondrite fell in California in 2012. The CM chondrite group is one of the most primitive, consisting of unequilibrated minerals, but some of them have experienced complex processes occurring on their parent body, such as aqueous alteration, thermal metamorphism, brecciation, and solar wind implantation. We have determined noble gas concentrations and isotopic compositions for SM samples using a stepped heating gas extraction method, in addition to mineralogical observation of the specimens. The primordial noble gas abundances, especially the P3 component trapped in presolar diamonds, confirm the classification of SM as a CM chondrite. The mineralogical features of SM indicate that it experienced mild thermal alteration after aqueous alteration. The heating temperature is estimated to be <350 °C based on the release profile of primordial ³⁶Ar. The presence of a Ni‐rich Fe‐Ni metal suggests that a minor part of SM has experienced heating at >500 °C. The variation in the heating temperature of thermal alteration is consistent with the texture as a breccia. The heterogeneous distribution of solar wind noble gases is also consistent with it. The cosmic‐ray exposure (CRE) age for SM is calculated to be 0.059 ± 0.023 Myr based on cosmogenic ²¹Ne by considering trapped noble gases as solar wind, the terrestrial atmosphere, P1 (or Q), P3, A2, and G components. The CRE age lies at the shorter end of the CRE age distribution of the CM chondrite group.  相似文献   

Particle size effect on the saturation of methane hydrate in sediments – Constrained from experimental results     

Hailong Lu  Tatsuji Kawasaki  Toshiyasu Ukita  Igor Moudrakovski  Tetsuya Fujii  Satoshi Noguchi  Tadaaki Shimada  Masaru Nakamizu  John Ripmeester  Chris Ratcliffe 《Marine and Petroleum Geology》2011,28(10):1801-1805

Except for those occurring at seafloor, most of natural gas hydrate form in sediments and are subject to the influence of sediment. Among these factors, the particle size effect on hydrate saturation level in sediment have been studied with a series of silica sands with various sizes, and the results obtained clearly indicate that particle size does play an important role in affecting the saturation level of hydrate in sediments. The proton relaxation times of water confined in the same series of silica sands, which were determined with NMR measurement, show logarithmic relationship with particle size. By comprehensive consideration of the results of hydrate saturation and water proton relaxation times, the particle size effect observed is tentatively explained by the water availability for hydrate formation in sediments.  相似文献   

Cosmogenic nuclides in the Brenham pallasite     

M. Honda  M. W. Caffee  Y. N. Miura  H. Nagai  K. Nagao  K. Nishiizumi 《Meteoritics & planetary science》2002,37(12):1711-1728

Abstract— Cosmic‐ray‐produced (cosmogenic) nuclides were studied in fragments of the Brenham pallasite, a large stony iron meteorite. The contents of light noble gases (He, Ne, and Ar) and long‐lived radionuclides (¹⁰Be, ²⁶Al, ³⁶Cl, and ⁵³Mn), produced by nuclear reactions with cosmic rays, were measured in the separated metal and olivine phases from numerous samples representing a wide range of shielding conditions in the meteoroid. The distribution of cosmogenic nuclide concentrations in the metal follows patterns similar to that observed in large iron meteorites. Shielding effects were estimated from the relative proportions of low‐ and high‐energy reaction products. The production rates varied, from surface to interior, by a factor of more than several hundred. The ³⁶Cl‐³⁶Ar cosmic‐ray exposure age of Brenham is 156 ± 8 Myr. This determination is based on a multiple nuclide approach that utilizes cosmogenic nuclide pairs. This approach not only yields a “shielding independent” exposure age but also demonstrates that the production of cosmogenic nuclides occurred in a single stage. The depth profiles of ¹⁰Be in the stone phase and ⁵³Mn in the metal phase are shown superimposed on corresponding profiles from the Apollo 15 long drill core. Surprisingly low abundances of lithophile elements, such as K, U, and Th, provided a unique opportunity to examine the production systematics of those nuclides whose inventories typically have significant contributions from non‐cosmogenic sources, particularly radiogenic contributions. The U and Th contents of the olivine samples are extremely low, allowing detection of cosmogenic ⁴He production from oxygen, magnesium, silicon, and iron.  相似文献   

Processes influencing iron distribution in the coastal waters of the Tsugaru Strait,Japan     

Yukiyo Saitoh  Kenshi Kuma  Yutaka Isoda  Hiroshi Kuroda  Hiromi Matsuura  Taku Wagawa  Hyoe Takata  Naoto Kobayashi  Seiya Nagao  Takeshi Nakatsuka 《Journal of Oceanography》2008,64(6):815-830

We report measurements of iron, nutrients, dissolved oxygen, humic-type fluorescence intensity and chlorophyll a concentrations in the coastal waters at the inflow (western) and outflow (eastern) ends of Tsugaru Strait (Japan) in June 2003 and 2004. Two different water masses (intensive eastward flow “subtropical Tsugaru Warm Current Water (TWCw)” and weak westward flow “subarctic Oyashio Water (OW)”) were observed at the eastern end of the strait. TWCw at the southern part of the eastern strait was vertically homogeneous with a uniform concentrations of iron (0.7–1.1 nM for labile dissolved Fe and 14–20 nM for total dissolvable Fe in 2003) as well as other chemical, biological and physical components throughout the water column of 200 m due to strong vertical mixing in the strait. The degree of mixing in the Tsugaru Warm Current (TWC) is predominantly affected by diurnal tidal current, which is strong during the period of tropical tides and weak during the period of equinoctial ones. The especially strong vertical water mixing in 2003 is caused by large dissipation energy input due to the bottom friction of passage-flow through the strait and tidal current. At the northern part of the eastern strait, the fresh surface layer overlying the OW and the deep-bottom waters in 2003 contained large concentrations of dissolved iron, resulting from iron supplied from river runoff and shelf sediments, respectively. These results suggest that the most important mechanism for transporting iron in the strait is the strong vertical water mixing due to the tidal current, and that the iron sources in the coastal waters are the organic-associated, iron-rich freshwater input into the surface water.  相似文献   

Juxtaposition of adakite, boninite, high-TiO₂ and low-TiO₂ basalts in the Devonian southern Altay, Xinjiang, NW China   总被引：1，自引：0，他引：1  

Hecai Niu  Hiroaki Sato  Haixiang Zhang  Jun'ichi Ito  Xueyuan Yu  Takashi Nagao  Kentaro Terada  Qi Zhang 《Journal of Asian Earth Sciences》2006,28(4-6):439-456

We present petrographic and geochemical data on representative samples of the Devonian adakite, boninite, low-TiO₂ and high-TiO₂ basalts and associated rocks in the southern Altay areas, Xinjiang, NW China. These volcanic rocks mostly occur as tectonic blocks within suture zones between the Siberian and Junggar plates. Adakite occurs in the Suoerkuduke area ca. 40 km south of Fuyun, and actually represents a poorly-sorted massive volcaniclastic deposit, mostly consisting of a suite of hornblende andesite to pyroxene andesite. The geochemical features of the adakite suggest its generation by melting of subducted oceanic crust. Boninite occurs in the Saerbulake area ca. 20 km southwest of Fuyun, as pillowed lava or pillowed breccia. It is associated with high-TiO₂ basalt/gabbro and low-TiO₂ basalt. The boninites are metamorphosed, but contain relict clinopyroxene with Mg# (=100*Mg/(Mg+Fe)) of 90–92, and Cr₂O₃ contents of 0.5–0.7 wt% and chromian spinel with Cr/(Cr+Al) ratio of 0.84. The bulk rock compositions of the boninites are characterized by low and U-shaped REE with variable La/Yb ratios. They are classified as high-Ca boninite. The Cr-rich cpx phenocryst and Chromian spinel suggests that the boninites were formed by melting of mildly refractory mantle peridotite fluxed by a slab-derived fluid component under normal mantle potential temperature conditions. Basaltic rocks occur as massive flows, pillowed lavas, tuff breccia, lapilli tuff and blocks in tectonic mélanges. Together with gabbros, the basaltic rocks are classified into high-TiO₂ (>1.7 wt%) and low-TiO₂ (<1.5 wt%) types. They show variable trace element compositions, from MORB-type through transitional back-arc basin basalt to arc tholeiite, or within plate alkalic basalt. A notable feature of the Devonian formations in the southern Altay is the juxtaposition of volcanic rocks of various origins even within a limited area; i.e. the adakite and the boninites are associated with high-TiO₂ and low-TiO₂ basalts and/or gabbros, respectively. This is most likely produced by complex accretion and tectonic processes during the convergence in the Devonian–Carboniferous paleo-Asian Ocean between the Siberian and Junggar plates.  相似文献   

Late Paleozoic adakites and Nb-enriched basalts from northern Xinjiang, northwest China: Evidence for the southward subduction of the Paleo-Asian Oceanic Plate   总被引：9，自引：0，他引：9  

Haixiang  Zhang  Hecai  Niu  Hiroaki  Sato  Xueyuan  Yu  Qiang  Shan  Boyou  Zhang  Jun'ichi  Ito  Takashi  Nagao 《Island Arc》2005,14(1):55-68

Abstract   Volcanic rocks consisting of adakite and Nb-enriched basalt are found in the early Devonian Tuoranggekuduke Group in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, northwest China. The geochemical characteristics of the andesitic and dacitic rocks in this area resemble that of adakites. The relatively high Al₂O₃, Na₂O and MgO content and Mg^♯ values indicate that the adakites were generated in relation to oceanic slab subduction rather than the partial melting of basaltic crust. A slightly higher SrI and a lower ɛ _Nd( t  = 375 Ma) compared to adakites of mid-oceanic ridge basalt (MORB) imply that slab sediments were incorporated into these adakites during slab melting. The Nb-enriched basalt lavas, which are intercalated in adakite lava suite, are silica saturated and are distinguished from the typical arc basalts by their higher Nb and Ti content (high field strength element enrichment). They are derived from the partial melting of the slab melt-metasomatized mantle wedge peridotite. Apparently, positive Sr anomalies and a slightly higher heavy rare earth element content in these adakites compared to their Cenozoic counterparts indicate that the geothermal gradient in the Paleo-Asian Oceanic subduction zone and the depth of the Paleo-Asian Oceanic slab melting are between those of their Archean and Cenozoic counterparts. The distribution of the adakites and Nb-enriched basalts in the northern margin of the Kazakhstan-Junggar Plate, northern Xinjiang, indicates that the Paleo-Asian Oceanic Plate subducted southward beneath the Kazakhstan-Junggar Plate in the early Devonian period.  相似文献   

Effective elastic thickness of island arc lithosphere under Japan   总被引：1，自引：0，他引：1  

Takeshi Kudo  Atsushi Yamaji  Muneyoshi Furumoto  Toshiyasu Nagao 《Island Arc》2001,10(2):135-144

Abstract Using topography and observed gravity anomalies, we have estimated the effective elastic thickness as a measure of strength of Japanese island arc lithosphere. The thickness is found to range from about 3 km to >20 km. The thickness seems to be controlled primarily by the thermal state of the lithosphere. The higher the heat flow, the thinner is the elastic plate. However, several areas show significant deviations. The smaller effective elastic thickness in the northern Ryukyu arc than that inferred from heat flow may be attributed to the stress regime. In Japan, extensional tectonics are going on only in the Ryukyu arc region. Shallow subducting slab under the south-western Japan frontal arc probably increases the effective thickness by several kilometers. The determined effective elastic thickness suggests that when we consider vertical movements in the volcanic arc, we should take account of topographic and subsurface loading over a few hundred kilometers. However, if the dip of the slab is shallow, the flexural responses of the underlying slab, not only that of the island arc lithosphere, should be taken into account for the compensation, as is the case of the south-western Japan frontal arc.  相似文献